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 Kinetic and Mechanistic Approach to the Oxidation of Some Selected Organic Acids

 سولو، أمنية محمد احسان


//uquui/handle/20.500.12248/117082
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Kinetic and Mechanistic Approach to the Oxidation of Some Selected Organic Acids

Alternative : نهج حركية وآلية أكسدة بعض الأحماض العضوية المختارة
Call Number : 23719
Publisher :جامعة أم القرى
Pub Place : مكة المكرمة
Issue Date : 2020 - 1441 H
Description : 284 ورقة.
Format : ماجستير
Department : الكيمياء
Language : انجليزي
Is format of : مكتبة الملك عبدالله بن عبدالعزيز الجامعية

This thesis concerns with a spectrophotometric investigation of the kinetics and mechanisms of oxidation of four selected significant organic acids; two of them are biologically reactive heterocyclic compounds, namely, barbituric and thiobarbituric acids, and two fatty acids, palmitic acid as a saturated acid, and linoleic acid as an unsaturated one by chromium trioxide in both aqueous and organic sulfuric and perchloric acidic media. In addition, study the influence of some metal ion catalysts on the kinetics of oxidation of both barbituric and thiobarbituric acids. Also, it presents a kinetic and mechanistic approach to the oxidation of thiobarbituric acid by hexacyanoferrate(III) in different acidic media, sulfuric and perchloric acids, as well as in alkaline media. Estimation of various activation and thermodynamic parameter for the oxidation processes are also undertaken.

Title: Kinetic and Mechanistic Approach to the Oxidation of Some Selected Organic Acids
Other Titles: نهج حركية وآلية أكسدة بعض الأحماض العضوية المختارة
Authors: سعد، أحمد فوزي
سولو، أمنية محمد احسان
Subjects :: Physical chemistry
Issue Date :: 2020
Publisher :: جامعة أم القرى
Abstract: This thesis concerns with a spectrophotometric investigation of the kinetics and mechanisms of oxidation of four selected significant organic acids; two of them are biologically reactive heterocyclic compounds, namely, barbituric and thiobarbituric acids, and two fatty acids, palmitic acid as a saturated acid, and linoleic acid as an unsaturated one by chromium trioxide in both aqueous and organic sulfuric and perchloric acidic media. In addition, study the influence of some metal ion catalysts on the kinetics of oxidation of both barbituric and thiobarbituric acids. Also, it presents a kinetic and mechanistic approach to the oxidation of thiobarbituric acid by hexacyanoferrate(III) in different acidic media, sulfuric and perchloric acids, as well as in alkaline media. Estimation of various activation and thermodynamic parameter for the oxidation processes are also undertaken.
Description :: 284 ورقة.
URI: https://dorar.uqu.edu.sa/uquui/handle/20.500.12248/117082
Appears in Collections :الرسائل العلمية المحدثة

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23719.pdfالرسالة الكاملة4.82 MBAdobe PDFView/Open
title23719.pdfغلاف223.34 kBAdobe PDFView/Open
indu23719.pdfالمقدمة1.42 MBAdobe PDFView/Open
cont23719.pdfفهرس الموضوعات235.52 kBAdobe PDFView/Open
abse23719.pdfملخص الرسالة بالإنجليزي74.19 kBAdobe PDFView/Open
absa23719.pdfملخص الرسالة بالعربي273.69 kBAdobe PDFView/Open
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